Dynamics of Coulombian systems

 

 

Vibrational spectroscopy of H2+

 

 

N. Billy, F. Bielsa, A. Douillet, L. Hilico, J.P. Karr, S. Killiç

Presentation
 

 

 

We are developing a two-photon spectroscopy experiment of the vibrational levels of the molecular ion H2+. The aim of the experiment is to measure the fundamental vibration frequency, and to deduce from it the proton to electron mass ratio, with a comparable or smaller relative uncertainty with respect to the most precise present determinations.

 

Ion trap

We have built a radiofrequency ion trap (Paul trap). The RF is about 10.7 MHz, the trap depth is a few eV. The trapped ions can be extracted from the trap and the ion species can be distinguished by time-of-flight measurement.

 

Piège à ions, zone de temps de vol et détecteur MCP

 

State selection of the ions

An excimer laser (KrF at 248 nm) will be used for selective photodissociation of ions in the vibrational levels v>0, allowing to prepare an ion cloud in the v=0 state.


Excitation of the two-photon transition

The two-photon transition between bound states of H2+ will be excited by a Quantum Cascade Laser (QCL) diode at 9.128 microns. The interest of this source is that it is tunable and yields a cw power of the order of 50 mW.
  The frequency of the QCL diode will be controlled by beating with a CO2 laser, itself stabilized using a saturated absorption signal in CO2.